低摩尔质量线形聚有机硅氧烷的物理常数（表2—8)
表2—8低摩尔质量线形聚有机硅氯烷的物理常数
|
化合物 |
黏度/
mPa • s (t) |
熔点/X： |
沸点（kPa) /V |
相对密度
C20t：) |
折射率
(20t：) |
|
(CH3)3SiOSKCH3)3 |
0. 412 (37. 8) |
—68 |
100.1 (100.9) |
0. 761 9 |
1. 377 4 |
|
CCH3)3SiOCCCH3)2SiO] Si(CH3)3 |
0.703 (37. 8) |
-86 |
151.7 (99. 59) |
0. 820 0 |
1. 384 8 |
|
(CH3)3SiOC(CH3)2SiO]2Si(CH3)3 |
1.09 (37.8) |
-76 |
194 (101.3) |
0.853 6 |
1. 389 5 |
|
(CH3)3SiOC(CH3)2SiO]3Si(CH3)3 |
1. 50 (37.8) |
-84 |
229 (101. 3) |
0. 875 5 |
1. 392 5 |
|
(CH3)3SiOC(CH3)2SiO]4Si(CH3)3 |
1.91 (37.8) |
-59 |
184.2 (13. 46) |
0. 891 0 |
1. 394 8 |
|
(CH3) 3 SiO[ (CH3) 2 SiO]5 Si( CH3) 3 |
2. 58 (37. 8) |
-78 |
184.5 (5. 33) |
0.911 |
1. 396 5 |
|
(CH3>3SiOC(CH3>2SiO]6Si(CH3)3 |
2.87 (37. 8) |
-63 |
202.0 (5. 24) |
0. 913 |
1. 397 0 |
|
(CH3)3SiO[(CH3)2SiO]7Si(CH3)3 |
3.38 (37. 8) |
|
198.8 (2.13) |
0.918 |
1. 398 0 |
|
(CH3)3SiOC(CH3)2SiO]8Si(CH3)3 |
3. 94 (37.8) |
|
202.8 (1. 33) |
0. 925 |
1. 398 8 |
|
(CH3)3SiO[(CH3)2SiO]9Si(CH3)3 |
4.52 (37.8) |
|
201. 8 (0. 626) |
0. 930 |
1. 399 4 |
|
(CH3 )3 SiO[CH3 (Ce Hs)SiO〕Si(CH3 )3 |
|
|
95 (0. 666) |
0. 908 0 |
1. 446 8 |
|
(CHshSiOLCHa (Ce Hs >SiO〕3Si(CH3 )3 |
13® (25) |
|
190 (0.0266) |
1.011 5 |
1.493 2 |
|
(CH3)3SiO[(C6H5)2SiO]SKCH3>3 |
7. 120 (25) |
-78 |
130 (0.036) |
0. 984 |
1. 498 1 |
|
(CH3)3SiO[(C6H5)2SiO]2Si(CH3)3 |
32 (50) |
40 |
208 (0.133) |
|
|
|
(CH3 )3SiOC(CH2—CH) (CH3 )SiO]SiCCH3 >3 |
|
|
78 <4.666) |
|
1. 396 2 |
|
(CH3)3SiOCCCH2—CH)(CH3)SiO]2Si(CH3)3 |
|
|
72 (0.266) |
|
1.414 6 |
|
(CH3)3SiO[(CH2=CH)(CH3)SiO]3Si(CH3)3 |
|
|
125〜129 (1.466) |
|
1.416 3 |
|
(CH3)3SiO[(CH2—CH)(CH3)SiO]4Si(CH3)3 |
|
|
142〜147 (1.333) |
|
1.419 8 |
|
(CH3)3SiO[(CH2—CH)(CH3)SiO]5SKCH3)3 |
|
|
167〜170 (0.266) |
|
1. 422 8 |
|
(CH3)3SiOCCH3CH)SiO] Si(CH3>3 |
|
|
142 (101. 3) |
0.819 4 |
1. 381 8 |
|
(CH3)3SiO[CH3(H)SiO]2Si(CH3)3 |
|
|
177 (101. 3) |
0. 855 9 |
1. 385 4 |
|
(CH3 )3 SiO[CH3 (H)SiO]3 Si(CH3 )3 |
|
|
85.6 (1.33) |
0.880 6 |
1. 387 8 |
|
(CH3 )3 SiOCCH3 (H)SiO]4 Si(CH3 )3 |
|
|
106.5 (1.33) |
0. 899 1 |
1, 389 5 |
|
(CH3 )3 SiOCCHa (H)SiO]5Si(CH3 )3 |
|
|
12 (0.133) |
|
1. 390 6 |
|
H(CH3)2SiOSKCH3)3 |
|
|
85.7 (101.3) |
0. 758 |
1. 378 9 |
|
H(CH3)2SiOSi(CH3>2H |
|
|
71.8 (101.3) |
0. 756 4 |
1. 369 4 |
|
H(CH3 ) 2 S1OCCH3 ( H)SiO]SKCH3 ) 2 H |
|
|
119 (101. 3) |
0. 825 |
1. 379 8 |
|
H(CH3)2SiOCCH3(H)SiO]2Si(CH3)2H |
|
|
157 (101.3) |
0- 867 |
1. 383 1 |
|
H(CH3)2SiOCCH3<H)SiO]3Si(CH3)2H |
|
|
188 (101.3) |
0. 884 |
1. 385 9 |
|
(CHz =CH) (CH3 )2 SiOSiCCHa )3 |
|
|
120 (101. 3) |
0. 787 |
I. 393 0 |
|
(CH2 =CH)(CH3)2SiOSi(CH3)2(CH=CH2) |
|
-99.7 |
139 (101.3) |
0. 811 |
1.412 3 |
|
(CH2 =CH) (CH3 > 2 S1OSKCH3 >2 H |
|
|
57 (17. 33) |
0. 784 |
1. 394 7 |
|
HOC(CH3)zSiO]2H |
|
67 〜68 |
|
1.095 |
1. 459 |
|
HOC(CH3)2SiO]3H |
|
|
79〜82 (0. 266) |
0. 999 9 |
1. 408 9 |
|
HOCCCH3)2SiO]4H |
|
|
97〜100 (0.266) |
0. 988 6 |
1. 405 4 |
|
HOC(CH3)2SiO]5H |
|
|
104—106 (0.20) |
0. 991 4 |
1. 408 9 |
|
HOL(CH3)2SiO]6H |
|
|
119〜120 (0.266) |
0_ 991 6 |
1. 409 9 |
|
HOC(CH3)2SiO]7H |
|
|
130〜135 (0.266) |
0. 989 1 |
1. 406 7 |
|
HOC(CH3)2SiO]8H |
|
|
143〜145 (0* 266) |
0. 991 2 |
1. 409 0 |
|
HOC(CH3)2SiO]9H |
|
|
158 〜161 (0.266) |
0. 992 1 |
1. 408 8 |
|
HOC(C�H5)2SiO]2H |
|
113〜114 |
|
|
|
|
HOC(CeH5)2SiO]3H |
|
111〜112 |
|
|
|
|
HOC(CfiH5)2SiO]4H |
|
128.5 |
|
|
|
|
CH3OC(CH3>2SiO]2CH3 |
0.79①(25) |
|
138 (101.3) |
0. 904 9 |
1. 383 6 |
|
CH30C(CH3)zSi0]3CH3 |
1.33①(25) |
|
180 (101. 3) |
0. 923 0 |
1. 389 0 |
|
CH3 0C(CH3)zSi0]4CH3 |
1.87①(25) |
|
216 (101. 3) |
0. 931 7 |
1. 392 3 |
|
CH30[(CH3)zSi0]5CH3 |
2. 51①（25) |
|
247 (101. 3) |
0.941 3 |
1. 394 9 |
|
化合物 |
黏度/
mPa • s (*C) |
熔点/t |
沸点(kPa)/*C |
相对密度 (20*C) |
折射率
(20t：) |
|
CH30[(CH3)2Si0]6CH3 |
3.11® (25) |
|
273 (101. 3) |
0. 947 0 |
1. 396 3 |
|
CH3OC(CH3)2SiO]7CH3 |
3. 60® (25) |
|
151 (0.133) |
0. 949 9 |
1.397 5 |
|
CH3 OC (CH3) 2 SiO]s ch3 |
4. 53①(25) |
|
165 (0.133) |
0.955 1 |
1.398 9 |
|
C2H5OC(CH3)2SiO]2C2H5 |
0. 97© (25) |
-134 |
161 (101.3) |
0. 878 8 |
1. 388 0 |
|
C2 H5 OC (CH3) 2 SiO] 3 Cz h5 |
1.35® (25) |
— 126 |
196 (101.3) |
0. 902 4 |
1. 392 2 |
|
C2 Hs OC(CH3) 2 SiO]4 C2 H5 |
1. 78® (25) |
-124 |
227 (101.3) |
0. 915 7 |
1. 395 0 |
|
C2HsO[(CH3)2SiO]sC2H5 |
2. 24© (25) |
-123 |
253 (101.3) |
0. 920 7 |
1. 396 4 |
|
C2HsOC(CH3)2SiO]fiC2H5 |
2. 75® (25) |
-118 |
274 (101.3) |
0. 931 7 |
1. 398 0 |
|
C2H5OC(CH3)2SiO]7C2H5 |
3. 28® (25) |
-112 |
292 (101.3) |
0. 934 6 |
1. 399 0 |
参考文献
[1] w •诺尔•硅洪化学与工艺学[M] •中国科学院兰州化学物理研究所三室，译.北京：科学出版社，1978.
[2] 晨光化工研究院有机硅编写组.有机硅单体及聚合物[M] •北京：化学工业出版社，1986.
[3] 李光亮.有机硅高分子化学[M].北京：科学出版社，1998.
[4] 幸松民，王一璐.有机硅合成工艺及应用[M].北京：化学工业出版社，2000.
[5] 黄文润.硅油及二次加工品[M].北京：化学工业出版社，2004.
[6] 冯圣王，等.有机硅高分子及其应用[M].北京：化学工业出版社，2004.
[7] DE 2, 521, 742, 1975.
[8] US Pat Appl bubl, 1981/310546.
[9] US, 4, 156, 689.
[10] 日本特开 2006—116380.
[11] 日本特公平3—19237.
[12] DE, 10349286.
[13] DE, 19727576.
[14] EP, 1046644.
[15] EP, 1046645.
[16] DE, 19619138.
[17] US, 6，037, 468.
[18] 日本特开，2002—205995.
[19] US, 2, 889, 379.
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